According to reports, Jolie photo was clicked by renowned photographer David LaChapelle when the actor was just 25 years old. This is expected to seek to 30,000 pounds.
Jolie "Billy Bob" tattoo of her ex-husband is also visible in this image. The auction will take place in the beautiful art auction house Christie's.
Another photo of Jolie and Pitt with their children is likely to sell at 10,000 pounds.